Taking female students in local colleges as the research object, this paper uses structural equation model to explore the structure of female college students' employability and its influencing factors. Through exploratory factor analysis, this paper obtains three potential variables: college employment training, college curriculum design and individual comprehensive quality. Through structural equation model, this paper explores the path load coefficient between potential variables and verifies the hypothesis. It is concluded that: College employment training has no significant impact on the improvement of female college students' employability; college curriculum design and individual comprehensive quality have a significant positive impact on the improvement of their employability. Based on the empirical research results, the paper puts forward relevant suggestions.