巢湖学院学报 ›› 2023, Vol. 25 ›› Issue (3): 108-112.doi: 10.12152/j.issn.1672-2868.2023.03.014

• 工程与技术 • 上一篇    下一篇

络合剂对LaSrFeCoO6催化剂制备及催化性能影响

郑建东,曹宇,朱启贤,杜佳佳:滁州学院 材料与化学工程学院   

  1. 滁州学院 材料与化学工程学院,安徽 滁州 239000
  • 收稿日期:2022-06-30 出版日期:2023-05-25 发布日期:2023-10-24
  • 作者简介:郑建东(1971—),男,河南南阳人,滁州学院材料与化学工程学院教授,博士,主要从事工业催化研究。
  • 基金资助:
    安徽省教育厅自然科学研究重大项目(项目编号:kJ2021ZD0135);滁州学院大学生创新项目(项目编号:2022CXXL093)

Effect of complexing agent on the Structure and Methane Combustion Activity of Catalyst LaSrFeCoO6

ZHENG Jian-dong,CAO Yu,ZHU Qi-xian,DU Jia-jia:College of Material and Chemical Engineering Chuzhou University   

  1. College of Material and Chemical Engineering Chuzhou University, Chuzhou Anhui 239000
  • Received:2022-06-30 Online:2023-05-25 Published:2023-10-24

摘要: 通过溶胶凝胶法,分别采用柠檬酸、酒石酸、葡萄糖、蔗糖、EDTA作为络合剂制备LaSrFeCoO6催化剂,以催化甲烷燃烧为目标反应,考察催化剂的活性。通过比表面积测定(BET)、X射线衍射分析(XRD)、氢还原(H2-TPR)、扫描电镜(SEM)及热分析(TG-DSC)等技术对催化剂进行性能表征。考察不同络合剂对LaSrFeCO6催化剂结构和性能影响。通过实验结果可以得到:经过800 ℃高温焙烧后,催化剂具有完整的钙钛矿晶型。不同络合剂对催化剂的结构和性能有较大影响;柠檬酸作为络合剂时,所制备LaSrFeCO6催化剂具有较好的催化活性,T10%(起燃温度)为 425 ℃,T90%(完全转化温度)为600 ℃。

关键词: 溶胶凝胶, 甲烷燃烧, LaSrFeCO6, 络合剂

Abstract: LaSrFeCoO6 was prepared by sol-gel method with different complexing agents (citric acid, tartaric acid, glucose, sucrose, EDTA). The title catalysts were characterized by XRD, BET, H2-TPR, TG-DSC and SEM techniques. The catalytic activity was evaluated for methane combustion. In the experiment different agents were used to prepare catalyst, which was calcined at 800 ℃ for three hours. The obtained catalyst has complete perovskite crystal. Different complexing agents have great influence on the structure and properties of the catalyst. When citric acid was used as the complexing agent, the LaSrFeCO6 catalyst had better catalytic activity; the conversion of 10% and 90% was obtained at 425 ℃ and 600 ℃, respectively.

Key words: sol-gel, methane combustion, LaSrFeCO6, complexing agent

中图分类号: 

  • TQ032