巢湖学院学报 ›› 2018, Vol. 20 ›› Issue (6): 55-61.
碳纳米管衍生物具有独特的物理、化学性质,有着广泛的应用前景,成为近年来的研究热点。碳纳米管衍生物的合成方法主要有有机共价键法和有机非共价键两种。有机共价键法主要是先将碳纳米管进行氧化产生活性基因,然后将其与其他官能团进行酰胺化、原位聚合、烷基化以及酯化等化学反应实现的;有机非共价键法则是通过在碳纳米管的表面进行包裹、缠绕或者接枝有机官能团分子。文章对碳纳米管衍生物的合成方法进行综述,着重介绍有机共价键法和有机非共价键法在合成碳纳米管衍生物方面的应用,并对合成方法存在的问题进行分析,同时对碳纳米管衍生物的应用前景进行了展望。
In recent years, carbon nanotubes derivatives become the research focus because of their unique physical and chemical characteristics and broad application prospect. Functionalized carbon nanotubes were synthetized mainly by the methods of#br# covalent bond and non-covalent bond. The former is the use of carbon nanotubes produced oxidation with other functional active groups occurring etherification, amidation, alkylation and in-situ polymerization reaction; The latter makes organic functional group molecular winding, coating or grafted in carbon nanotubes surface by non-covalent bond. In this paper, the synthesis methods of carbon nanotubes derivatives are reviewed, especially the methods of covalent bond and non-covalent bond are introduced. The existing problems of the synthesis methods are also analyzed. In the meantime, the application prospect of nanotubes derivatives is discussed.#br#
摘要: 碳纳米管衍生物具有独特的物理、化学性质,有着广泛的应用前景,成为近年来的研究热点。碳纳米管衍生物的合成方法主要有有机共价键法和有机非共价键两种。有机共价键法主要是先将碳纳米管进行氧化产生活性基因,然后将其与其他官能团进行酰胺化、原位聚合、烷基化以及酯化等化学反应实现的;有机非共价键法则是通过在碳纳米管的表面进行包裹、缠绕或者接枝有机官能团分子。文章对碳纳米管衍生物的合成方法进行综述,着重介绍有机共价键法和有机非共价键法在合成碳纳米管衍生物方面的应用,并对合成方法存在的问题进行分析,同时对碳纳米管衍生物的应用前景进行了展望。
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